Consider striking a tuning fork producing a sound wave. The tuning fork vibrates at some frequency. The fork pushes air molecules away which them push other air molecules away and so forth. Without air molecules, nothing is pushed, and nothing happens. No sound is produced.
Thus if you are in space and yell to someone (not through a radio, that's different), they can see you yelling, but can't hear you. This means that big explosions in space produce no sound. Makes for a more boring movie, but a more scientifically correct movie.
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